Matheus Cunha struck twice and Vinícius Júnior added a stoppage-time third as Brazil cruised past Haiti and into the knockouts.
Without the injured Pulisic, the USA saw off Australia 2-0 to seal their place in the Round of 32.
A single Luis Romo strike just after half-time sent Mexico through to the Round of 32 at the Azteca.
Jonathan David scored a hat-trick as Canada produced the rout of the group stage, thumping Qatar 6-0.
Harry Kane scored twice and Jude Bellingham struck the decisive blow as England edged a six-goal thriller with Croatia.
Brazil secured a 3-0 win against Haiti in their World Cup match, restoring some confidence in their campaign.
Yoane Wissa's first-half equaliser earned Congo DR a famous point against Portugal on their World Cup bow.
Lionel Messi rolled back the years with a hat-trick as the holders Argentina swept past Algeria.
Erling Haaland marked his long-awaited World Cup debut with two goals as Norway beat Iraq 4-1.
Kylian Mbappé scored twice as France opened with a 3-1 win over a spirited Senegal.
Breel Embolo's first-half penalty looked like enough for Switzerland — until Miro Muheim turned into his own net in the 90th minute.
Tunisia's head coach Sabrei Lamouchi dismissed following a 5-1 defeat to Sweden in World Cup opener.
Amad Diallo struck at the death to settle a tight contest and give Ivory Coast all three points.
Eric Just scored twice for New Zealand, but Iran hit back each time to share a four-goal thriller.
Goals from Nestory Irankunda and Connor Metcalfe gave Australia a composed 2-0 win over Türkiye in Vancouver.
Twice behind, Japan refused to fold — and Daichi Kamada's 89th-minute strike earned a famous point against the Netherlands.
Kai Havertz scored twice and Deniz Undav had a hand in three goals as Germany ran riot against Curaçao.
John McGinn's first-half strike was enough to give Scotland a hard-earned opening win over Haiti.
Ismael Saibari put Morocco ahead inside 21 minutes before Vinícius Júnior levelled, and Brazil were grateful for the draw.
Cape Verde dug in for a goalless draw that counts as the tournament's first big upset.